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用API 函数GetVolumeInformation得到的不是硬盘的序列号！！！
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BOOL GetVolumeInformation(
LPCTSTR lpRootPathName,
LPTSTR lpVolumeNameBuffer,
DWORD nVolumeNameSize,
LPDWORD lpVolumeSerialNumber,
LPDWORD lpMaximumComponentLength,
LPDWORD lpFileSystemFlags,
LPTSTR lpFileSystemNameBuffer,
DWORD nFileSystemNameSize
);
看看英文啊：VolumeSerialNumber!得到的只是卷区序列号！
硬盘的序列号应该是
Drive Model Number________________: WDC WD400EB-00CPF0
Drive Serial Number_______________: WD-WCAATF083586
Drive Controller Revision Number__: 06.04G06
Controller Buffer Size on Drive___: 2097152 bytes
Drive Type________________________: Fixed
Drive Size________________________: 40020664320 bytes
中：
Drive Serial Number_______________: WD-WCAATF083586 这才是硬盘Serial Number！！！！
这个号是不会因为你格式化硬盘而改动，也不是网上流传的修改工具能改的，（其实网上流传的修改工具的也不过是卷区号而已！）
建议用 DiskID.dll或DiskID32.dll来获取
用diskid.dll和disk32.dll获得硬盘序列号
1.调用diskid.dll实现：
Option Explicit
Private Declare Function IsWinNT Lib "DiskID.DLL" () As Long
Private Declare Function ReadPhysicalDrive9X Lib "DiskID.DLL" (driveID As Long, buffer As Long, bufLen As Long) As Long
Private Declare Function ReadPhysicalDriveInNT Lib "DiskID.DLL" (driveID As Long, buffer As Long, bufLen As Long) As Long
Private Type DRIVER_INFO_OK
ModalNumber(39) As Byte
SerialNumber(19) As Byte
ControlNum(7) As Byte
DriveType As Long
Cylinders As Long
Heads As Long
Sectors As Long
End Type
Private Sub Command1_Click()
Dim x As DRIVER_INFO_OK
Dim i As Long
If IsWinNT = 1 Then
i = ReadPhysicalDriveInNT(ByVal 0, ByVal VarPtr(x), ByVal 256)
Else
i = ReadPhysicalDrive9X(ByVal 0, ByVal VarPtr(x), ByVal 256)
End If
Dim s As String
s = StrConv(x.ModalNumber, vbUnicode)
s = Left(s, InStr(1, s, Chr(0)) - 1)
MsgBox "硬件厂商代码为：" + s
s = StrConv(x.SerialNumber, vbUnicode)
s = Left(s, InStr(1, s, Chr(0)) - 1)
MsgBox "硬盘序列号为：" + s
End Sub
2.调用diskid32.dll实现：
Option Explicit
Private Declare Function DiskID32 Lib "DiskID32.DLL" (ByRef DiskModel As Byte, ByRef DiskID As Byte) As Long
Private Sub Command1_Click()
Dim DiskModel(31) As Byte, DiskID(31) As Byte, i As Integer, Model As String, ID As String
If DiskID32(DiskModel(0), DiskID(0)) 1 Then
MsgBox "get diskid32 err"
Exit Sub
End If
For i = 0 To 31
If Chr(DiskModel(i)) Chr(0) Then
Model = Model Chr(DiskModel(i))
End If
If Chr(DiskID(i)) Chr(0) Then
ID = ID Chr(DiskID(i))
End If
Next
MsgBox "硬件产生代码为：" + Model
MsgBox "硬盘序列号为：" + ID
End Sub
说明：diskid.dll可从下载
diskid32.dll可从下载
首先使用 System.IO.DriveInfo.GetDrives()获取System.IO.DriveInfo，存入ds()
然后遍历ds，获取各个信息部分。
Dim ds() As System.IO.DriveInfo = System.IO.DriveInfo.GetDrives()
For i As Integer = 0 To ds.Length - 1
TextBox1.Text = TextBox1.Text + ds(i).DriveType.ToString + " " '驱动器类型
TextBox1.Text = TextBox1.Text + ds(i).Name + " " '盘符（驱动器名）
TextBox1.Text = TextBox1.Text + ds(i).IsReady.ToString + " " '是否就绪
If ds(i).IsReady = True Then
TextBox1.Text = TextBox1.Text + ds(i).VolumeLabel + " " '卷标
TextBox1.Text = TextBox1.Text + ds(i).TotalSize.ToString + " " '驱动器容量
TextBox1.Text = TextBox1.Text + ds(i).TotalFreeSpace.ToString '驱动器可用容量
End If
TextBox1.Text = TextBox1.Text + vbNewLine
Next
预先准备三个图标文件，用于树型控件中显示磁盘符号和文件夹的图像之用。
1、窗体上添加控件如下：
组合框控件 ComboBox1，树型控件 TreeView1，列表框控件 ListBox1，图像列表控件 ImageList1。
选中TreeView1，设置其ImageList属性为ImageList1。
2、设置属性
选中图像列表控件 ImageList1，在属性窗口里，选中属性Images，单击三个小点按钮，出现图像集合编辑器窗口，单击[添加按钮]，一一把准备好的图标文件进行添加，注意先后次序，如果不符合要求可以通过上下移动按钮重新改变次序。完成后单击[确定]。
运行图如下：
完整代码如下：
Imports System.IO
Public Class Form1
Private Sub Form1_Load(ByVal sender As System.Object, ByVal e As System.EventArgs) Handles MyBase.Load
'添加系统所有磁盘目录符号
For Each MyDrive As String In Environment.GetLogicalDrives()
ComboBox1.Items.Add(MyDrive)
Next
'显示第一个磁盘符号
ComboBox1.Text = ComboBox1.Items(0)
End Sub
'递归过程添加目录树
Public Sub AddDirectory(ByVal strFatherPath As String, ByVal strPath As String, ByVal nodeFather As TreeNode)
Dim i As Integer
Dim Mynode As New TreeNode
'先添加本目录
Mynode.Text = Strings.Replace(strPath, strFatherPath "\", "", , 1)
'为节点指定未被选中时显示的图标
Mynode.ImageIndex = 1
'为节点指定被选中时显示的图标
Mynode.SelectedImageIndex = 2
nodeFather.Nodes.Add(Mynode)
Application.DoEvents()
Try
Dim str() As String = Directory.GetDirectories(strPath)
'递归遍历该目录的子文件夹
For i = 0 To str.GetUpperBound(0)
AddDirectory(strPath, str(i), Mynode)
Next
Catch ex As Exception
Debug.WriteLine(ex.Message)
End Try
Mynode = Nothing
End Sub
'根据给出的盘符添加目录树
Private Sub AddRootDirectory(ByVal DiscSymbol As String)
Dim Nynode As New TreeNode
'先把磁盘盘符添加到树中
TreeView1.Nodes.Clear()
Nynode.ImageIndex = 0
Nynode.Text = DiscSymbol
Nynode.SelectedImageIndex = -1
TreeView1.Nodes.Add(Nynode)
Dim i As Integer
'获取磁盘根目录下的文件夹
Dim str() As String = Directory.GetDirectories(DiscSymbol "\")
For i = 0 To str.GetUpperBound(0)
'调用递归过程遍历该文件夹里的所有子文件夹，并添加到树型控件
AddDirectory(DiscSymbol, str(i), Nynode)
Next
Nynode = Nothing
End Sub
Private Sub ComboBox1_SelectedIndexChanged(ByVal sender As System.Object, ByVal e As System.EventArgs) Handles ComboBox1.SelectedIndexChanged
'根据磁盘符号的变更，显示根目录里的文件
ListBox1.Items.Clear()
For Each MyFile As String In System.IO.Directory.GetFiles(ComboBox1.Text)
ListBox1.Items.Add(MyFile)
Next
'根据磁盘符号的变更，重新显示目录树
Dim DiscSymbol As String
DiscSymbol = Microsoft.VisualBasic.Left(ComboBox1.Text, Len(ComboBox1.Text) - 1)
Call AddRootDirectory(DiscSymbol)
End Sub
'递归过程根据子目录寻找上级目录名--从而构成完整的目录路径
Private Sub AllPath(ByVal ThisNode As TreeNode, ByRef MyPathName As String)
If ThisNode.Level 1 Then
'该节点层数大于1，其父节点不是磁盘根目录
MyPathName = ThisNode.Parent.Text "\" MyPathName
Dim MyNode As TreeNode = ThisNode.Parent
Call AllPath(MyNode, MyPathName)
Else
'该节点层数等于1，其父节点就是磁盘根目录
MyPathName = ComboBox1.Text MyPathName
End If
End Sub
Private Sub TreeView1_AfterSelect(ByVal sender As System.Object, ByVal e As System.Windows.Forms.TreeViewEventArgs) Handles TreeView1.AfterSelect
'为了搜索选中的节点对应目录的文件，需要组成全路径
Dim MyAllPathName As String = TreeView1.SelectedNode.Text
Dim MyNode As TreeNode = TreeView1.SelectedNode
If TreeView1.SelectedNode.Level = 0 Then
'如果选中的是根节点
MyAllPathName = ComboBox1.Text
Else
'如果选中的是非根节点，调用递归过程组成全路径
Call AllPath(MyNode, MyAllPathName)
MyAllPathName = MyAllPathName "\"
End If
'根据路径，搜索文件名并显示
ListBox1.Items.Clear()
For Each MyFile As String In System.IO.Directory.GetFiles(MyAllPathName)
ListBox1.Items.Add(MyFile)
Next
End Sub
End Class